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You don't actually need a sketchy PDF download to access the core information. Because of the book's importance to public safety and scientific record, the Shulgins allowed much of the technical data to be hosted openly: Erowid’s Online Archive

If you cannot afford the book, use Erowid. If you need the synthesis data for academic purposes, use the Shulgin Archives. But if you want to understand why a chemist would try 200 drugs on himself and call it a "love story"—buy the book. Set aside the $40. And read it under a tree. pihkal pdf free

If you are a student of pharmacology: Instead, search for the excerpts of Part II on Erowid. The knowledge is there, legally, for free. You don't actually need a sketchy PDF download